Gas temperature dependent sticking of hydrogen on cold amorphous water ice surfaces of interstellar interest.

نویسندگان

  • E Matar
  • H Bergeron
  • F Dulieu
  • H Chaabouni
  • M Accolla
  • J L Lemaire
چکیده

Using the King and Wells method, we present experimental data on the dependence of the sticking of molecular hydrogen and deuterium on the beam temperature onto nonporous amorphous solid water ice surfaces of interstellar interest. A statistical model that explains the isotopic effect and the beam temperature behavior of our data is proposed. This model gives an understanding of the discrepancy between all known experimental results on the sticking of molecular hydrogen. Moreover, it is able to fit the theoretical results of Buch et al. [Astrophys. J. 379, 647 (1991)] on atomic hydrogen and deuterium. For astrophysical applications, an analytical formula for the sticking coefficients of H, D, H(2), D(2), and HD in the case of a gas phase at thermal equilibrium is also provided at the end of the article.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Changes in the morphology of interstellar ice analogues after hydrogen atom exposure.

The morphology of water ice in the interstellar medium is still an open question. Although accretion of gaseous water could not be the only possible origin of the observed icy mantles covering dust grains in cold molecular clouds, it is well known that water accreted from the gas phase on surfaces kept at 10 K forms ice films that exhibit a very high porosity. It is also known that in the dark ...

متن کامل

Sticking probability and mobility of a hydrogen atom on icy mantle of dust grains

The sticking and the diffusion processes of a hydrogen atom on the surface of icy mantle of dust grains have been investigated based on the classical molecular dynamics (MD) simulation. As themodel for the icymantle, a slab-shaped amorphous water ice with infinite area was generated by MD simulation under the periodic boundary condition. It was found that the densities and the oxygen-oxygen dis...

متن کامل

Mobility of D atoms on porous amorphous water ice surfaces under interstellar conditions

Aims. The mobility of H atoms on the surface of interstellar dust grains at low temperature is still a matter of debate. In dense clouds, the hydrogenation of adsorbed species (i.e., CO), as well as the subsequent deuteration of the accreted molecules depend on the mobility of H atoms on water ice. Astrochemical models widely assume that H atoms are mobile on the surface of dust grains even if ...

متن کامل

Experimental study of water-ice catalyzed thermal isomerization of cyanamide into carbodiimide: implication for prebiotic chemistry.

Cyanamide (NH2CN) is a molecule of interstellar interest which can be implied in prebiotic chemistry. We showed, by FTIR spectroscopy, that cyanamide can be isomerized in carbodiimide (HNCNH), another interstellar relevant molecule, by a reaction involving the amorphous water-ice surface as catalyst. This isomerization occurs at low temperature (T < 100 K) which agrees quite well with that expe...

متن کامل

A Comparison of Oxidized Carbon Abundances among Comets

Comets contain relatively well preserved icy material remaining from the epoch of Solar System formation, however the extent to which these ices are modified from their initial state remains a fundamental question in cometary science. As a comet approaches the Sun, sublimation of the ices contained in its nucleus (termed "native ices") releases parent volatiles into the coma, where they can be ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • The Journal of chemical physics

دوره 133 10  شماره 

صفحات  -

تاریخ انتشار 2010